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What Do Coolant Test Results Mean?

by Ed Thaves
President, S.C. Chemical Company, Inc.
www.scchemical.com



The objective in writing about coolants on a regular basis is to inform those who use coolants of all the “secrets” about coolants so you never have to think about coolant again. In the February 2006 issue of Shop Talk you read, “Don’t change coolant suppliers over price!” Introducing you to the idea that pricing is relative and many coolant suppliers have a “value added” service that you can’t put a price tag on.

In the May 2006 issue of Shop Talk you read, “Five steps to improve total coolant performance.” We thought this was such a good topic, we invited 300 coolant users to a one day seminar just to talk about what can be done to save money when using coolants.

With this background information the next logical step is to explain the results of testing coolant from your shop. Let’s consider that you already have a coolant supplier you trust. Then, you implement the “five steps”:

1. Improving water source

2. Removing tramp oil

3. Removing metal fines

4. Controlling concentration

5. Using the right coolant to begin with

Now, your coolant supplier visits you on a regular basis and takes samples from various machines for analysis in their laboratory. The whole idea here is to evaluate the condition of the coolant and make recommendations that will prevent problems and extend the life of the coolant. But what if you receive a “lab report” and you don’t know what it means? Let me help you out!

A typical lab report will list:

1. Coolant concentration

2. pH

3. Bacteria level

4. Fungus/mold level

5. Percentage of tramp oil

6. Percentage sediment

7. Rust test

Let’s look at each of these to get a better understanding of what the tests results mean.

Coolant concentration

Here we measure the strength of the mixture of your coolant. Depending on the product you are using and the machining operation, your concentration may vary anywhere from four percent to 10 percent, sometimes higher with exotic metals. Whatever the specific circumstances it is important to maintain the coolant at a consistent concentration. For example, if you are machining cast iron and using your coolant at five percent concentration, from day to day you will notice a change in the concentration. Water evaporates so the coolant concentration increases. The coolant deposits rust preventive on parts and coolant is carried off with chips so the concentration decreases. Slight variations in concentration are acceptable; so a five percent solution should be designed to work well at 4.5 percent or at 5.5 percent without creating any difficulty. Problems do arise when the coolant concentration goes outside these limits. As the coolant concentration decreases, when only water is added to the sump, rust protection starts to suffer along with tool performance. At lower concentrations you aren’t lubricating the tool. The other extreme is too high a concentration. Here, tool life will improve; but by continuing to increase the concentration, operators are more likely to develop skin irritations. With the use of a “refractometer,” you can maintain your coolant on a daily basis and avoid problems.

pH

pH measures the degree of alkalinity or acidity of a solution. This is important to you because as the coolant’s pH value changes, so does the coolant’s ability to protect against rust and product instability. pH is a number on a scale from 0-14. On this scale 7 is neutral, below 7 is acidic and above 7 is alkaline. Typical coolant pH values are 8.5 to 9.2; this may vary slightly with the particular coolant you are using. The coolant’s pH value will change from week to week depending on what is happening with the coolant. When bacteria are rapidly growing your pH value will move from 9.2 towards 8.5 and perhaps even lower. If there is a contaminant such as a cleaner (cleaners are usually alkaline) you may see your coolant’s pH increase.

Why measure pH? By watching pH over time, a chemist will be able to forecast what may happen to the coolant in the future. Taken by itself, one pH reading does not tell us a lot. But numerous readings over time allow us to predict future coolant performance and stability.

Bacteria, fungus, and mold

These tests inform us of the biological condition of the coolant. What harmful things are growing in the coolant? Bacteria are ever-present in our world. High levels of bacteria start to smell bad and will also degrade the quality of the coolant. Coolants are typically designed to provide resistance to bacteria, fungus, and mold; however, sometimes the biology in the coolant takes over. Why would this happen? If your coolant concentration gets too low, the ability of the coolant to fight off bacteria is impaired. Diluting the coolant dilutes any biocide or fungicide that may be in the coolant to help protect it. The by-product of bacteria in your coolant is acidic which causes the pH to move from an alkaline position to an acidic position. This can affect rust protection and over time degrade the coolant even further.

Testing for bacteria, fungus, and mold will help determine what steps need to be taken to keep the coolant fresh.

Percentage of tramp oil

Tramp oil is unavoidable because before this oil became “tramp” oil, it was your hydraulic oil or gear lube that helped the machine function. Now, since it’s leaked into the coolant we call it “tramp” oil. A little unfair, I know! Tramp oil is a contaminant to the coolant and must be removed. Levels above one percent can be a real problem because this oil, floating on the coolant, prevents the coolant from breathing (taking in oxygen) and allows types of bacteria known as anaerobic bacteria (bacteria that live and breed in the absence of oxygen) to multiply quickly. This explains why a machine sump with heavy tramp oil might smell bad on Monday mornings. The coolant sat all weekend and the oil came to the surface, sealing off the oxygen and the bacteria took over. You start the coolant up on Monday and it smells terrible for 20-30 minutes until the bacteria are killed off by oxygen. Removing tramp oil not only helps prevent bacteria from taking over, it gives your coolant longer sump life.

Percentage of sediment

One of the other contaminants in the coolant is sediment. This is dirt introduced from the air or from the surfaces of parts. It is also carbon from the metal you are machining and metal fines that the filter didn’t remove. Removing sediment may require some special filters or magnetic separators. Acknowledging that sediment is present allows the chemist to make proper recommendations to improve your coolant performance.

Testing for rust

For the rust test, we take a small Petri dish with filter paper on the bottom and add 1.0 gram of cast iron chips (special chips of uniform size and shape designed just for this ASTM procedure). Then, we add enough coolant to cover the chips and allow the dish to set for a short period of time. Once the coolant is removed the dish is left undisturbed for 48 hours; then, the chips are examined for rust. If your coolant concentration was maintained at the proper level, your laboratory report will likely indicate “no rust.” Otherwise, you may have “slight rust” on the edges of the chips, “moderate rust” on the surface of the chips, or “severe rust” where the chips weld themselves together.

Conclusion

Taking proper care of coolant isn’t as difficult as it may seem, especially if you have a partnership with a coolant company that provides laboratory testing of your coolant. All of the tests described above are relatively easy to run. The results from all these tests help the chemist or the sales representative diagnose the condition of your coolant and write the proper prescription for improving coolant health. Just like a visit to the doctor!

If you have low coolant concentration and tramp oil, you will probably see increased bacteria levels and a lower pH. If this condition goes untreated, the coolant will get “sicker” and the bacteria level will continue to rise and start to smell bad. The lower pH will also cause the coolant to underperform and your tool life will decline drastically. All this could be avoided with proper diagnosis and treatment

Please keep in mind that regular testing of coolant concentration along with removal of tramp oil and metal fines will greatly improve the condition of your coolant and allow it to last a good long time. There are also other tests that can be run to evaluate a coolant’s condition that are not included in this article. We have covered the most important tests; but, if you have any questions, give me a call at 1-888-729-0176.

 


This article originally appeared in Shop Talk magazine in August of 2006. Shop Talk is published by Magellan Publishing.

S.C. Chemical Company, Inc. S84 W18757 Saturn Drive, Muskego, WI 53150
P.O. Box 510085 New Berlin, WI 53151 | Toll Free (888) 729-0176
(262) 971-9903 | Fax (262) 971-9905
Email edt@scchemical.com